A new field instrument developed by a team of researchers at the University of Colorado at Boulder can detect and quantify methane leaks as tiny as one-quarter of a human exhalation from nearly a mile away.
The revamped laser technology — based on Nobel Prize-winning science developed at CU Boulder — turns a room-sized collection of instruments into a single, 19-inch portable unit to tote into the field near oil and natural gas operations. The instrument collects precise, nonstop data, providing information for not only safe industry operations, but also controlling greenhouse gas emissions.
The team is comprised of scientists from the CU College of Engineering and Applied Science, the Cooperative Institute for Research in Environmental Sciences, the National Oceanic and Atmospheric Administration and National Institute of Standards and Technology (NIST). The project was funded by an ARPA-E grant.
Detecting methane and other gas leaks from oil and gas operations has traditionally been hampered by high costs and technological constraints, which have limited efforts to provide continuous monitoring. The new technology, which relies on a laser system called a dual frequency comb spectrometer, provides efficient and accurate data collection at a fraction of the cost of previous technologies.
“This instrument is particularly special because it’s precise, autonomous, and continuous,” said Caroline Alden, a CIRES researcher and a co-lead author of the study. “Other technologies like aircraft flybys or physically traveling to sampling sites pose a problem. If a leak occurs between sampling events, you missed it.”
Continuous monitoring could help industry operators catch not only frequent, small leaks, but large, infrequent ones, Alden said. Such “super emitters” are thought to comprise only 20 percent of leaks, but cause 80 percent of emissions.
The journey to this technology started in 2005, when researchers won the Nobel Prize in physics for work on a device called a frequency comb laser. The laser emits hundreds of thousands of wavelengths of light, compared with the single wavelength of many traditional lasers. This laser enables the measurement of light with extreme accuracy, enabling precision atomic clocks and future mapping technologies, for example.
Other researchers realized a frequency comb could also be used to measure concentrations of specific molecules in the air, as each would have their own light absorption “fingerprint.” Researchers Nate Newbury and Ian Coddington made this possible by creating a frequency comb spectrometer capable of untangling the thousands of different wavelengths from the device.
When it came to applying this technology to real-world methane leak detection, a team including principal investigator Greg Rieker, atmospheric scientist Alden, chemist Sean Coburn and engineer Rob Wright stepped in. The team scaled down what was originally a room brimming with instrumentation to a 19-inch box that could be carried into the field. Alden and others on the atmospheric team figured out how to use wind patterns to investigate possible leak points, enabling their frequency-comb based observing system to pinpoint the source of a methane leak.
“It was a great collaborative effort, it all came together perfectly,” Rieker said. “We ended up creating an instrument that was mobile, portable and robust. It works better than the original at a 10th of the cost.”
The instrument sits on a mobile platform that can be placed in field sites surrounded by oil and gas operations. It swivels 360 degrees, sending out carefully tuned, invisible beams of light to reflect off small mirrors placed a mile or more away. If the beam, composed of over 100,000 wavelengths, passes through part of a gas plume blowing like a ribbon through the air, gases in the plume absorb some of the light in the beam before it returns to the detector. This lets researchers identify the unique absorption “fingerprints” of gases like methane and carbon dioxide. And with atmospheric models, researchers can track back to an actual leak location.
Researchers first tested the dual frequency comb spectrometer observing system at Boulder’s Table Mountain research facility, successfully detecting leaks emitted from large metal cylinders full of methane they dragged around the rolling hills of the field site. The team is now putting the instrument through a rigorous blind test: collaborators at a test site set up by the Energy Institute at Colorado State University offered a treasure hunt of leaks in varying locations and sizes, even planting false leaks to trick the system.
“We know nothing about the leaks or where they are — so there will be no cheating the system,” Rieker said. “We’re still preparing those results for public release, but I can say that we surprised even ourselves with our ability to find the leaks.”
This technology presents something unique in the oil and gas industry: the ability to monitor hundreds of sites from a single location. The more locations you can measure with a single instrument, the more cost effective it becomes, Alden said
“As part of an effort to provide a service that can give oil and gas operators more efficient and cheaper leak detection, we are launching a start-up called Longpath Technologies,” Alden said. “We will continue to grow this alongside the emerging technology it relies on.”